SYNTHESIS OF ALLENIC NAPHTHALENE DERIVATIVES

Ramazan Erenler

doi:10.4314/bcse.v21i2.21203

download PDF

Published:

Jul 10, 2007

DOI:

10.4314/bcse.v21i2.21203

Keywords:

Isomerisation Allenic derivatives of naphthalene

Issue

Vol. 21 No. 2 (2007)

Section

Articles

Ramazan Erenler

Department of Chemistry, Faculty of Art and Science, Gaziosmanpasa University, 60240 Tokat, Turkey

Abstract

Propargylic alcohol of naphthalene derivatives were synthesized and converted to the corresponding propargylic acetate using acetic anhydride. Reduction of the propargylic acetates by SmI₂ afforded allenes and acetylenes. Base-promoted isomerisation of acetylene formed allene in high yield.

KEY WORDS: Isomerisation, Allenic derivatives of naphthalene

Bull. Chem. Soc. Ethiop. 2007, 21(2), 241-247.

Bulletin of the Chemical Society of Ethiopia
Journal / Bulletin of the Chemical Society of Ethiopia / Vol. 21 No. 2 (2007) / Articles

Published:

DOI:

Keywords:

<b>SYNTHESIS OF ALLENIC NAPHTHALENE DERIVATIVES</b>

Ramazan Erenler

Abstract

Journal Identifiers

Article Sidebar

Published:

DOI:

Keywords:

Article Details

Main Article Content

Ramazan Erenler

Abstract

Journal Identifiers