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Synthesis, infrared and mossbauer studies of two new oxalato SnPh<sub>2</sub>Cl<sub>2</sub> and SnPh<sub>2</sub>Cl(OH) adducts
Abstract
Two new oxalato chloridodiorganostannic adducts have been synthesized, their elemental analyses performed, infrared and Mossbauer studies carried out. Discrete cages or a double discrete cages structures have been suggested, the oxalate behaving as a monocoordinating or a monochelating donor. The key role of R2NH2+ cations, involved in NH…O hydrogen bonds is noteworthy.
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Keywords: Diorganostannic residues, infrared, Mossbauer, cage, coordinating oxalate.
