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The Free-Radical Copolymerization of Difurylmethane with Maleic Anhydride


WAA Ddamba
JC Ngila
TT Mokoena
K Motlhagodi

Abstract

The copolymerization of difurylmethane with maleic anhydride in the presence of azobisisobutyronitrile as an initiator has been investigated at 65 ºC, 72 ºC and 85 ºC in different solvents. Reaction feeds containing 85 mol % and higher of difurylmethane yielded a soluble alternating copolymer in which the furan residue entrained in the polymer chain formed 2,5 linkages and had 3,4 unsaturation. The 1:1 difurylmethane- maleic anhydride adduct was readily prepared, and at the above temperatures and in the presence of the radical initiator partially underwent retro-Diels-Alder reaction. Copolymerization of the difurylmethane and maleic anhydride thus formed yielded the unsaturated alternating copolymer. Copolymers prepared from reaction feeds with proportions of difurylmethane lower than 85 mol % had higher cross-link density and exhibited higher thermodecomposition temperatures.


South African Journal of Chemistry Vol.55 2002: 1-12

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eISSN: 1996-840X
print ISSN: 0379-4350