Stability of binary complexes of Pb(II), Cd(II) and Hg(II) with maleic acid in TX100-water mixtures
Binary complexes of maleic acid with toxic metal ions such as Pb(II), Cd(II) and Hg(II) have been studied in 0.0-2.5% v/v tritonX-100 (TX100) - water media at 303 K at an ionic strength of 0.16 M. The active forms of the ligand are LH2, LH- and L2-. The derived ‘best fit’ chemical speciation models are based on crystallographic R-factors, χ2 and Skewness and Kurtosis factors. The predominant species formed are of the type ML2, ML2H and ML3. The trend in variation of complex stability constants with change in the mole fraction of the medium is explained on the basis of prevailing electrostatic and non-electrostatic forces. The species distribution as a function of pH at different compositions of TX100-water mixtures and plausible speciation equilibria are presented and discussed.
KEY WORDS: Maleic acid, TritonX-100, Toxic metal ions, Mole fraction, Binary complexes
Bull. Chem. Soc. Ethiop. 2014, 28(3), 383-391.