Main Article Content

Efficient and convenient synthesis of symmetrical carboxylic anhydrides from carboxylic acids with sulfated zirconia by phase transfer catalysis


Yu Lin Hu
Xing E Zhao
Ming Lu

Abstract

An efficient and convenient procedure for the synthesis of symmetrical carboxylic anhydrides from carboxylic acids with sulfated zirconia by PEG-1000 phase transfer catalysis has been developed. The reactions proceeded under mild and solvent-free conditions to provide the carboxylic anhydrides in good to excellent yields. The product can be isolated by a simple extraction with organic solvent, and the catalyst system can be recycled or reused without any significant loss of catalytic activity.

KEY WORDS: Carboxylic anhydrides, Carboxylic acids, SO42-/ZrO2, Phase transfer catalysis

 

Bull. Chem. Soc. Ethiop. 2011, 25(2), 255-262.

Journal Identifiers


eISSN: 1726-801X
print ISSN: 1011-3924