Synthesis, infrared and mossbauer studies of two new oxalato SnPh2Cl2 and SnPh2Cl(OH) adducts

  • Y Sow
  • L Diop
  • JD Ardisson

Abstract

Two new oxalato chloridodiorganostannic adducts have been synthesized, their elemental analyses performed, infrared and Mossbauer studies carried out. Discrete cages or a double discrete cages structures have been  suggested, the oxalate behaving as a monocoordinating or a monochelating donor. The key role of R2NH2+ cations, involved in NH…O hydrogen bonds is noteworthy.

© 2013 International Formulae Group. All rights reserved.

Keywords: Diorganostannic residues, infrared, Mossbauer, cage, coordinating oxalate.

Published
2014-03-27
Section
Articles

Journal Identifiers


eISSN: 1997-342X
print ISSN: 1991-8631