Synthesis, infrared and mossbauer studies of two new oxalato SnPh2Cl2 and SnPh2Cl(OH) adducts
Two new oxalato chloridodiorganostannic adducts have been synthesized, their elemental analyses performed, infrared and Mossbauer studies carried out. Discrete cages or a double discrete cages structures have been suggested, the oxalate behaving as a monocoordinating or a monochelating donor. The key role of R2NH2+ cations, involved in NH…O hydrogen bonds is noteworthy.
© 2013 International Formulae Group. All rights reserved.
Keywords: Diorganostannic residues, infrared, Mossbauer, cage, coordinating oxalate.
Submission of a paper for publication implies the transfer of the copyright from the author(s) to the publisher upon acceptance. International Formulae Group is therefore the copyright holder after publication of an article in International Journal of Biological and Chemical Sciences, and published articles should not be used for commercial purpose without the written consent of the Editor-in-Chief. They are licensed under a Creative Commons Attribution-Non Commercial-Share Alike 4.0 International License.