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Bulletin of the Chemical Society of Ethiopia

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AM1 and electron impact mass spectrometry study of the fragmentation of 4-acyl isochroman-1,3-diones

Abdoulaye Djandé, Bintou Sessouma, Félix B. Kini, Leopold Kaboré, Bayo Karifa, Pierre I. Guissou, Adama Saba

Abstract


Recently, in electron impact mass spectrometry (EIMS), it has been found a good correlation between the fragmentation processes of coumarins and the electronic charges of the atoms of their skeleton. In this paper, the same analytical method has been applied to 4-acyl isochroman-1,3-diones, whose mass spectra had been studied earlier and described for the very first time from our laboratory. Results obtained are in good agreement with the last study.

 

KEY WORDS: 4-Acyl isochroman-1,3-dione, Electron impact mass spectrumetry, AM1, Electronic charges, Fragmentation

 

Bull. Chem. Soc. Ethiop. 2012, 26(2), 311-318.

DOI: http://dx.doi.org/10.4314/bcse.v26i2.15




http://dx.doi.org/10.4314/bcse.v26i2.15
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