Photovoltaic performance of dye-sensitized solar cell based on eosin-Y photosensitizer and quasi-solid state electrolyte
AbstractDye-sensitized solar cells (DSSCs), as low-cost photovoltaic devices compared to the silicon based solar cells, have received extensive attention recently; although much work is necessary to reach optimal device efficiencies. This paper reports the fabrication and characterization of dye sensitized solar cells using TiO2 sensitized by eosin-Y. The electrodes, electrolyte (I−∕I3−), and dyes were assembled into a cell and illuminated by a light with an intensity 100 mWcm-2 to measure the photoelectrochemical parameters of the prepared DSSCs. According to the experimental results, the maximum quantum efficiency appeared at the wavelength of 510 nm with IPCE of 64.2%. The short circuit current density (JSC), the open circuit voltage (VOC), and power conversion efficiency (η%) were measured to be 6.4 mAcm-2, 0.54 V, and 2.2%, respectively. The result of UV-visible absorption and IPCE measurement showed that the IPCE correlated to the absorption spectrum of the active layer. The IPCE and η% obtained in the present work was higher than the values reported earlier for the liquid state electrolyte system indicating that the quasi-solid-state electrolyte could substitute the liquid state.
Bai, Y., Cao, Y.M., Zhang, J., Wang, M.K., Li, R.Z., Wang, P., Zakeeruddin, S.M and Grätzed, M. (2008). High-performance dye-sensitized solar cells based on solvent-free electrolytes produced from eutectic melts. Nature Materials 7: 626-630.
Baviskar, P., Ennaoui, A and Sankapal, B. (2014). Influence of processing parameters on chemically grown ZnO films with low cost eosin-Y dye towards efficient dye sensitized solar cell. Solar Energy 105: 445–454.
Chen, D., Zhang, Q., Wang, G., Zhang, H and Li, J.-H. (2007). A novel composite polymer electrolyte containing room-temperature ionic liquids and heteropolyacids for dye-sensitized solar cells. Electrochemical Communications 9: 2755-2759.
Chuan-P.L., Chun-T.L. and Kuo-C.H. (2017). Use of organic materials in dye-sensitized solar cells, Materials Today 20(5): 267-283.
Fan, L.; Kang, S.; Wu, J.; Hao, S.; Lan, Z and Lin, J. (2010). Quasi-solid-state dye-sensitized solar cells based on polyvinylpyrrolidone with ionic liquid. Energy Sources A 32: 1559-1568.
Grätzel, M. (2004). Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells. Journal Phot hemistry and Photobiology A 164: 3-14.
Hagfeldt, A., Boschloo, G., Sun, L., Kloo, L and Pettersson, H. (2010). Dye-sensitized solar cells. Chemical Review 110: 6595–6663.
Hugo, W.B and Newton, J.M. (1963). The Solubility of iodine in aqueous solutions on non-ionic surface-active agents. Journal of Pharmacy and Pharmacology 15: 731-741.
Katsaros, G., Stergiopoulos, T., Arabatzis, I.M., Papadokostaki, K.G and Falaras, P. (2002). A solvent-free composite polymer/inorganic oxide electrolyte for high efficiency solid-state dyesensitized solar cells. Journal of Photochemistry and Photobiology A 149: 191–198.
Kim, D.W., Jeong, Y.B., Kim, S.H., Lee, D.Y and Song, J.S. (2005). Photovoltaic performance of dye-sensitized solar cell assembled with gel polymer electrolyte. Journal of Power Sources 149: 112–116.
Krüger, J., Plass, R., Grätzel, M and Matthieu, H.J. (2002). Improvement of the photovoltaic performance of solid-state dye-sensitized device by silver complexation of the sensitizer cis-bis (4,40-dicarboxy-2,20-bipyridine)-bis (isothiocyanato) ruthenium. Applied Physics Letter 81: 367-369.
Kuang, D.B., Wang, P., Ito, S., Zakeeruddin, S.M and Grätzel, M. (2006). Stable mesoscopic dye-sensitized solar cells based on tetracyanoborate ionic liquid electrolyte. Journal of American Chemical S iety 128: 7732-7733.
Kumara, G.R.A., Kaneko, S., Okuya, M and Tennakone, K. (2002). Fabrication of dye-sensitized solar cells using triethylamine hydrothiocyanate as a CuI crystal growth inhibitor. Langmuir 18: 10493-10495.
Kusama, H., Kurashige, M and Arakawa, H. (2005). Influence of nitrogen-containing heterocyclic additives in I-/I3- redox electrolytic solution on the performance of Ru-dye-sensitized nanocrystalline TiO2 Solar Cell. Journal of Photochemistry and Photobiology A 169(2): 169-176.
Meidan, Y., Xiaoru, W., Mengye, W., James, I., Nan, Z., Changjian, L and Zhiqun, L. (2015). Recent advances in dye-sensitized solar cells: from photoanodes, sensitizers and electrolytes to counter electrodes. Materials Today 18(3): 155-162.
Muhammad, Z. I., Syeda, R.A and Sana, K. (2019). Progress in dye sensitized solar cell by incorporating natural photosensitizers. Solar Energy 181: 490-509.
Nazeeruddin, M.K., Angelis, F.D., Fantacci, S., Selloni, A., Viscardi, G., Liska, P., Ito, S., Takeru, B and Grätzel, M. (2005). Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers. Journal of American Chemical Society 127: 16835-16847.
Nazeeruddin, M.K., Baranoff, E and Grätzel, M. (2011). Dye-sensitized solar cells: A brief overview. Solar Energy 85: 1172-1178.
Nazeeruddin, M.K., Kay, A., Rodicio, I., Humphry-Baker, R., Muller, E., Liska, P., Vlachopoulos, N and Grätzel, M. (1993). Conversion of light to electricity by cis-X2Bis(2,20-bipyridyl-4,40-dicarboxylate) ruthenium (II) charge-transfer sensitizers (X = C1-, Br-, I-, CN-, and SCN-) on nanocrystalline TiO2 electrodes. Journal of American Chemical Society 115: 6382-6390.
O’Regan, B and Grätzel, M. (1991). A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353: 737-740.
O’Regan, B., Lenzmann, F., Muis, R and Wienke, J. (2002). A solid-state dye-sensitized solar cell fabricated with pressure-treated P25-TiO2 and CuSCN: Analysis of pore filling and IV characteristics. Chemistry of Materials 14: 5023-5029.
Reddy, C.V.S., Han, X., Zhu, Q.Y., Mai, L.Q and Chen, W. (2006). Dielectric spectroscopy studies on (PVP + PVA) polyblend film. Microelectronic Engineering 83(2): 281-285.
Smestad, G.P., Spiekermann, S., Kowalik, J., Grant, C.D., Schwartzberg, A.M., Zhang, J., Tolbert, L.M and Moons, E. (2003). A technique to compare polythiophene solid-state dye sensitized TiO2 solar cells to liquid junction devices. Solar Energy Materials and Solar Cells 76: 85-105.
Stathatos, E., Lianos, P., Zakeeruddin, S.M., Liska, P and Grätzel, M. (2003). A quasi-solid-state dye-sensitized solar cell based on a sol-gel nanocomposite electrolyte containing ionic liquid. Chemistry of Materials 15: 1825-1829.
Suri, P., Panwar, M and Mehra, R.M. (2007). Photovoltaic performance of dye-sensitized ZnO solar cell based on Eosin-Y photosensitizer. Materials Science-Poland 25(1): 137-144.
Vinodgopal, K., Hua, X., Dalgren, R.L., Lappin, A.G., Patterson, L.K and Kamat, P.V. (1995). Photochemistry of Ru(bpy)2(dcbpy)2+ on Al2O3 and TiO2 surfaces. An insight into the mechanism of photosensitization. Journal of Physical Chemistry 99(27): 10883-10889.
Wang, P., Zakeeruddin, S.M., Exnar, I and Grätzel, M. (2002). High efficiency dye-sensitized nanocrystalline solar cells based on ionic liquid polymer gel electrolyte. Chemical Communications 2972–2973.
Wang, P., Zakeeruddin, S.M., Moser, J.E and Grätzel, M. (2003a). A new ionic liquid electrolyte enhances the conversion efficiency of dye-sensitized solar cells. Journal of Physical Chemistry B 107: 13280-13285.
Wang, P., Zakeeruddin, S.M., Moser, J.E., Nazeeruddin, M.K., Sekiguchi, T and Grätzel, M. (2003b). A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer electrolyte. Nature Materials 2: 402-407.
Wu, J.H., Hao, S.C., Lan, Z., Lin, J.M., Huang, M.L., Huang, Y.F., Fan, L.Q., Yin, S and Sato, T. (2007). A thermoplastic gel electrolyte for stable quasi-solid-state dye-sensitized solar cells. Advanced Functional Materials 19: 4006-011.
Yang, C.C., Zhang, H.Q and Zheng, Y.R. (2011). DSSC with a novel Pt counter electrode using pulsed electroplating techniques. Current Applied Physics 11: S147-S153.
Zafer, C., Karapire, C., Sariciftci, N.S and Icli, S. (2005). Characterization of N, N-bis-2-(1-hydroxy-4-methylpentyl)-3,4,9,10-perylene bis(dicarboximide) sensitized nanocrystalline TiO2 solar cells with polythiophene hole conductors. Solar Energy Materials and Solar Cells 88: 11-21.